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Abstract Ionization drives important chemical and dynamical processes within protoplanetary disks, including the formation of organics and water in the cold midplane and the transportation of material via accretion and magnetohydrodynamic flows. Understanding these ionization-driven processes is crucial for understanding disk evolution and planet formation. We use new and archival Atacama Large Millimeter/submillimeter Array observations of HCO⁺, H¹³CO⁺, and N₂H⁺to produce the first forward-modeled 2D ionization constraints for the DM Tau protoplanetary disk. We include ionization from multiple sources and explore the disk chemistry under a range of ionizing conditions. Abundances from our 2D chemical models are postprocessed using non-LTE radiative transfer, visibility sampling, and imaging, and are compared directly to the observed radial emission profiles. The observations are best fit by a modestly reduced cosmic-ray ionization rate (ζ_CR∼10⁻¹⁸s⁻¹) and a hard X-ray spectrum (hardness ratio = 0.3), which we associate with stellar flaring conditions. Our best-fit model underproduces emission in the inner disk, suggesting that there may be an additional mechanism enhancing ionization in DM Tau’s inner disk. Overall, our findings highlight the complexity of ionization in protoplanetary disks and the need for high-resolution multiline studies. 

Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a few specific PAHs have been detected in the interstellar medium. We detected 1-cyanopyrene, a cyano-substituted derivative of the related four-ring PAH pyrene, in radio observations of the dense cloud TMC-1, using the Green Bank Telescope. The measured column density of 1-cyanopyrene is $\sim \text{1}{\text{.52×10}}^{\text{12}}$cm⁻², from which we estimate that pyrene contains up to 0.1% of the carbon in TMC-1. This abundance indicates that interstellar PAH chemistry favors the production of pyrene. We suggest that some of the carbon supplied to young planetary systems is carried by PAHs that originate in cold molecular clouds. 

Abstract We explore terrestrial planet formation with a focus on the supply of solid-state organics as the main source of volatile carbon. For the water-poor Earth, the water ice line, or ice sublimation front, within the planet-forming disk has long been a key focal point. We posit that the soot line, the location where solid-state organics are irreversibly destroyed, is also a key location within the disk. The soot line is closer to the host star than the water snow line and overlaps with the location of the majority of detected exoplanets. In this work, we explore the ultimate atmospheric composition of a body that receives a major portion of its materials from the zone between the soot line and water ice line. We model a silicate-rich world with 0.1% and 1% carbon by mass with variable water content. We show that as a result of geochemical equilibrium, the mantle of these planets would be rich in reduced carbon but have relatively low water (hydrogen) content. Outgassing would naturally yield the ingredients for haze production when exposed to stellar UV photons in the upper atmosphere. Obscuring atmospheric hazes appear common in the exoplanetary inventory based on the presence of often featureless transmission spectra. Such hazes may be powered by the high volatile content of the underlying silicate-dominated mantle. Although this type of planet has no solar system counterpart, it should be common in the galaxy with potential impact on habitability. 

Abstract An understanding of abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H 2 O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few astronomical units of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H 2 18 O traces deeper into this layer and will trace the full content of the planet-forming zone. In this work, we explore the relative distribution of H 2 16 O and H 2 18 O within a model that includes water self-shielding from the destructive effects of ultraviolet radiation. In this Letter we show that there is an enhancement in the relative H 2 18 O abundance high up in the warm molecular layer within 0.1–10 au due to self-shielding of CO, C 18 O, and H 2 O. Most transitions of H 2 18 O that can be observed with JWST will partially emit from this layer, making it essential to take into account how H 2 O self-shielding may effect the H 2 O to H 2 18 O ratio. Additionally, this reservoir of H 2 18 O -enriched gas in combination with the vertical “cold finger” effect might provide a natural mechanism to account for oxygen isotopic anomalies found in meteoritic material in the solar system. 

Abstract The radial transport, or drift, of dust has taken a critical role in giant planet formation theory. However, it has been challenging to identify dust drift pileups in the hard-to-observe inner disk. We find that the IM Lup disk shows evidence that it has been shaped by an episode of dust drift. Using radiative transfer and dust dynamical modeling we study the radial and vertical dust distribution. We find that high dust drift rates exceeding 110M_⊕Myr⁻¹are necessary to explain both the dust and CO observations. Furthermore, the bulk of the large dust present in the inner 20 au needs to be vertically extended, implying high turbulence (α_z≳ 10⁻³) and small grains (0.2–1 mm). We suggest that this increased level of particle stirring is consistent with the inner dust-rich disk undergoing turbulence triggered by the vertical shear instability. The conditions in the IM Lup disk imply that giant planet formation through pebble accretion is only effective outside of 20 au. If such an early, high-turbulence inner region is a natural consequence of high dust drift rates, then this has major implications for understanding the formation regions of giant planets including Jupiter and Saturn. 

Abstract Observations of substructure in protoplanetary disks have largely been limited to the brightest and largest disks, excluding the abundant population of compact disks, which are likely sites of planet formation. Here, we reanalyze ∼0.″1, 1.33 mm Atacama Large Millimeter/submillimeter Array (ALMA) continuum observations of 12 compact protoplanetary disks in the Taurus star-forming region. By fitting visibilities directly, we identify substructures in six of the 12 compact disks. We then compare the substructures identified in the full Taurus sample of 24 disks in single-star systems and the ALMA DSHARP survey, differentiating between compact (R_eff,90%< 50 au) and extended (R_eff,90%≥50 au) disk sources. We find that substructures are detected at nearly all radii in both small and large disks. Tentatively, we find fewer wide gaps in intermediate-sized disks withR_eff,90%between 30 and 90 au. We perform a series of planet–disk interaction simulations to constrain the sensitivity of our visibility-fitting approach. Under the assumption of planet–disk interaction, we use the gap widths and common disk parameters to calculate potential planet masses within the Taurus sample. We find that the young planet occurrence rate peaks near Neptune masses, similar to the DSHARP sample. For 0.01M_J/M_⊙≲M_p/M_*≲0.1M_J/M_⊙, the rate is 17.4% ± 8.3%; for 0.1M_J/M_⊙≲M_p/M_*≲1M_J/M_⊙, it is 27.8% ± 8.3%. Both of them are consistent with microlensing surveys. For gas giants more massive than 5M_J, the occurrence rate is 4.2% ± 4.2%, consistent with direct imaging surveys. 

Abstract The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary-building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV shielding to be able to increase the emission of organics. Here, we expand on these models and investigate how UV shielding may impact chemical composition in the inner 5 au. In this work, we use the model from Bosman et al. and expand it with a larger chemical network. We focus on the chemical abundances in the upper disk atmosphere where the effects of water UV shielding are most prominent and molecular lines originate. We find rich carbon and nitrogen chemistry with enhanced abundances of C₂H₂, CH₄, HCN, CH₃CN, and NH₃by >3 orders of magnitude. This is caused by the self-shielding of H₂O, which locks oxygen in water. This subsequently results in a suppression of oxygen-containing species like CO and CO₂. The increase in C₂H₂seen in the model with the inclusion of water UV shielding allows us to explain the observed C₂H₂abundance without resorting to elevated C/O ratios as water UV shielding induced an effectively oxygen-poor environment in oxygen-rich gas. Thus, water UV shielding is important for reproducing the observed abundances of hydrocarbons and nitriles. From our model result, species like CH₄, NH₃, and NO are expected to be observable with the James Webb Space Telescope (JWST). 

Abstract Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestrial planet-forming zone, the inner few astronomical units, of protoplanetary disks. The species currently detected in the disk atmosphere, for example, CO, CO₂, H₂O, and C₂H₂, are theoretically enough to constrain the C/O ratio on the disk surface. However, thermochemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into the thermochemical code Dust and Lines. We find that both are required to match the observed emission spectrum. Efficient chemical heating, in addition to traditional heating from UV photons, is necessary to elevate the temperature of the water-emitting layer to match the observed excitation temperature of water. We find that water UV-shielding stops UV photons from reaching deep into the disk, cooling down the lower layers with a higher column. These two effects create a hot emitting layer of water with a column of 1–10 × 10¹⁸cm⁻². This is only 1%–10% of the water column above the dustτ= 1 surface at mid-infrared wavelengths in the models and represents <1% of the total water column.